Oxidation-reduction reactions are those that involve the movement of electrons or electrons from one particle to another.
Redox reactions are therefore made up of two half-processes that occur together: the losing of electrons or oxidation, and the gaining of electrons or reduction.
An oxidation number is a positive or negative number assigned to an atom to indicate its degree of oxidation or reduction.
In binary ionic compounds, the oxidation numbers of the atoms equal their ionic charges.
The oxidation number of hydrogen in a compound is +1, except in metal hydrides, such as NaH, where it is –1.
The oxidation number of oxygen in a compound is –2, except in peroxides, such as H2O2, where it is –1, and in compounds with the more electronegative fluorine, where it is positive.
The oxidation number of an atom in uncombined (elemental) form is 0.
For any neutral compound, the sum of the oxidation numbers of the atoms in the compound must equal 0.
For a polyatomic ion, the sum of the oxidation numbers must equal the ionic charge of the ion.