3.1.9.1 Rate Expression

Cards (84)

  • The rate in a rate expression represents the speed at which the reaction occurs.

    True
  • In a chemical equation, the starting substances are called reactants
  • The general form of a rate expression is Rate = k[A]^m[B]^n.
  • In a chemical equation, the new substances formed are called products
  • The order of reaction with respect to each reactant is indicated by its exponent
  • The order of reaction with respect to each reactant is determined experimentally
  • The rate expression for a reaction A + B → Products is given by Rate = k[A]^m[B]^n, where m and n are the orders
  • Match the overall order with its corresponding rate dependence:
    Zero order ↔️ Rate is independent of reactant concentrations
    First order ↔️ Rate is directly proportional to [A]
    Second order ↔️ Rate is proportional to [A]² or [A][B]
  • What are the orders of reaction with respect to hydrogen and iodine in the reaction H₂ + I₂ → 2HI?
    1 and 1
  • What are the reactants in the chemical equation 2H₂ + O₂ → 2H₂O?
    H₂ and O₂
  • In a zero-order reaction, the rate is independent of the reactant's concentration
  • The general rate expression is Rate = k[A]^m[B]^n, where m and n represent the orders of reaction with respect to [A]
  • The overall order of reaction is the sum of the individual orders with respect to each reactant
  • The empirical rate expression is determined experimentally
  • In the rate expression, k represents the rate constant
  • The rate constant is influenced by the reaction mechanism, temperature, and the presence of catalysts
  • The rate constant (k) is influenced by temperature and catalysts.
    True
  • The rate constant (k) changes with reactant concentrations.
    False
  • Order the components of a rate expression from simplest to most complex:
    1️⃣ Reactant concentrations
    2️⃣ Rate constant
    3️⃣ Reaction orders
    4️⃣ Rate
  • The rate expression for the reaction H₂ + I₂ → 2HI is Rate = k[H₂][I₂], where m = 1 and n = 1, indicating the reaction is first order with respect to both hydrogen and iodine.
  • Match the term with its effect on reaction rate:
    Zero Order ↔️ Rate independent of concentration
    First Order ↔️ Rate directly proportional to concentration
    Second Order ↔️ Rate increases by square of concentration
  • The order of reaction with respect to each reactant describes how the concentration of a reactant affects the rate of the reaction.
  • In a first-order reaction, the rate is directly proportional to the concentration
  • The overall order of reaction is the sum of the individual orders with respect to each reactant
  • What is the rate expression for the reaction 2NO + O₂ → 2NO₂?
    Rate = k[NO]²[O₂]
  • What could be the empirical rate expression for the reaction 2N₂O₅ → 4NO₂ + O₂?
    Rate = k[N₂O₅]
  • Given k = 0.05 M⁻²s⁻¹, [A] = 0.2 M, [B] = 0.3 M, m = 1, and n = 2, what is the rate of the reaction?
    0.0009 M/s
  • The rate constant k is influenced by temperature and catalysts
  • What is the mathematical equation that describes how the rate of a chemical reaction depends on reactant concentrations called?
    Rate Expression
  • Match the term with its definition:
    Rate ↔️ Speed of the reaction
    k ↔️ Rate constant
    [A], [B] ↔️ Concentrations of reactants
    m, n ↔️ Orders of reaction
  • Reactants are found on the left side of the arrow in a chemical equation.
    True
  • Match the term with its definition:
    Rate ↔️ Speed of the reaction
    k ↔️ Rate constant
    [A], [B] ↔️ Concentrations of reactants
    m, n ↔️ Orders of reaction
  • Products are found on the right side of the arrow in a chemical equation.
    True
  • Match the order of reaction with its effect on rate:
    Zero Order ↔️ Rate independent of concentration
    First Order ↔️ Rate directly proportional to concentration
    Second Order ↔️ Rate increases by the square of concentration
  • In a zero-order reaction, the rate is independent of the reactant's concentration.

    True
  • Arrange the reactions in order based on their overall reaction orders, from lowest to highest:
    1️⃣ NH₄NO₂ → N₂ + 2H₂O; Rate = k (Zero order)
    2️⃣ 2N₂O₅ → 4NO₂ + O₂; Rate = k[N₂O₅] (First order)
    3️⃣ H₂ + I₂ → 2HI; Rate = k[H₂][I₂] (Second order)
  • In a zero-order reaction, the rate expression is Rate = k.
    True
  • Match the term in a rate expression with its definition:
    Rate ↔️ Speed of the chemical reaction
    k ↔️ Rate constant
    [A], [B] ↔️ Concentrations of reactants
    m, n ↔️ Orders of reaction
  • Arrange the effect on reaction rate based on the reaction order, from least to most affected:
    1️⃣ Zero order: Independent of concentration
    2️⃣ First order: Directly proportional to concentration
    3️⃣ Second order: Increases by the square of concentration
  • What is the relationship between the rate and reactant concentration in a first-order reaction?
    Directly proportional