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Edexcel A-Level Chemistry
Core Practicals
CP4 Finding the Activation Energy of a Reaction
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Activation Energy is the minimum energy required to initiate a chemical
reaction
Activation energy represents the energy barrier that
reactants
must overcome for a reaction to proceed.
What is the mathematical expression for the Arrhenius Equation?
k
=
k =
k
=
A
e
−
E
a
R
T
Ae^{ - \frac{E_{a}}{RT}}
A
e
−
RT
E
a
In the Arrhenius Equation, the frequency factor (
A
A
A
) reflects the number of collisions and orientation
The ideal gas constant (R) in the Arrhenius Equation is 8.314 \, J \, mol^{ - 1} \,
K
^{ - 1}</latex>.
Arrange the components in the experimental setup for rate determination in the correct order:
1️⃣ Reactants
2️⃣ Temperature control
3️⃣ Concentration adjustment
4️⃣ Stirring rate
5️⃣ pH control
Temperature in the experimental setup can be controlled using a water
bath
Volumetric flasks are used to prepare solutions of known
concentration
in the experimental setup.
What is used to ensure uniform distribution of reactants in the experimental setup?
Magnetic stirrer
Reactants in the experimental setup must have precise amounts and
concentrations
Match the variable in the Arrhenius Equation with its meaning:
k
k
k
↔️ Rate of a reaction
A
A
A
↔️ Frequency and orientation of collisions
E
a
E_{a}
E
a
↔️ Activation energy
T
T
T
↔️ Absolute temperature in Kelvin
The Arrhenius Equation demonstrates that as temperature increases, the reaction rate decreases.
False
What does the Arrhenius Equation relate the rate constant of a reaction to?
Temperature and activation energy
In the Arrhenius Equation, the symbol
k
k
k
represents the rate constant.
What does the frequency factor
A
A
A
in the Arrhenius Equation reflect?
Collision frequency and orientation
Activation energy is measured in
J
/
m
o
l
J / mol
J
/
m
o
l
.
The ideal gas constant
R
R
R
has a value of 8.314 J \, mol^{ - 1} \, K^{ - 1}</latex>.
What is the unit of absolute temperature in the Arrhenius Equation?
Kelvin
Steps to determine the rate of a reaction in an experimental setup
1️⃣ Control reaction conditions
2️⃣ Use specific equipment
3️⃣ Measure reaction parameters
What is the purpose of using precise amounts and concentrations of reactants in a reaction?
Ensure purity and control
Temperature is controlled in a reaction using a water bath or temperature-controlled
environment
.
A magnetic stirrer ensures uniform distribution of
reactants
in the reaction mixture.
What does a buffer solution or pH meter maintain in a reaction mixture?
Desired pH level
As temperature increases, the value of e^{ - \frac{E_{a}}{RT}}</latex> becomes less
negative
.
The reaction rate always increases linearly with temperature.
False
Key steps in data collection and recording for reaction kinetics
1️⃣ Identify and control variables
2️⃣ Use precise instruments
3️⃣ Record data systematically
What type of data table is used to record measurements in reaction kinetics experiments?
Well-structured data table
Clear and organized data tables ensure reproducibility of
experimental
results.
To calculate the rate constant
k
k
k
, you need the reaction rate and the rate equation.
What is the minimum amount of energy needed to initiate a chemical reaction called?
Activation energy
Activation energy represents the energy barrier that reactants must overcome to form
products
.
What is the mathematical expression that relates the rate constant of a reaction to its temperature and activation energy called?
Arrhenius Equation
In the Arrhenius Equation, the frequency factor
A
A
A
reflects collision frequency and orientation.
What does the rate constant (
k
k
k
) measure in a chemical reaction?
Speed of the reaction
The frequency factor (
A
A
A
) reflects the collision frequency and orientation
What are the units of activation energy (
E
a
E_{a}
E
a
)?
J
/
m
o
l
J / mol
J
/
m
o
l
Higher activation energy (
E
a
E_{a}
E
a
) results in a faster reaction rate.
False
The Arrhenius Equation relates the rate constant to temperature and
activation
What is the mathematical expression of the Arrhenius Equation?
k
=
k =
k
=
A
e
−
E
a
R
T
Ae^{ - \frac{E_{a}}{RT}}
A
e
−
RT
E
a
As temperature increases, the rate constant (
k
k
k
) also increases.
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